This simply tells you which of your Facebook friends is online right now.
The next Facebook Chat tool is notifications which will let you know if you have any new Facebook notifications right from the tool.
They'll get the message when they're back online.
When you log into Facebook you're automatically logged into Facebook Chat so you can chat on Facebook.
Just go to your Facebook page and you can start to chat on Facebook right away.
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This is certainly a personal choice and one that Facebook Chat lets you have.